Well I'm a lot happier!
After sealing the sump return chamber to prevent CO2 loss I gained some improvement but it still wasn't good.
I then altered the standpipe to reduce turbulence and gained another improvement but still couldn't stop all the CO2 gassing off within 4 hours of CO2 going off. It was also taking 4+ hours to build it up again and I couldn't get it below about 25ppm.
After thinking about it I had an epiphany (it's OK, I'm taking medication for it!

) Atmospheric gas was being dragged down the standpipe through the ventilation hose (it follows a Durso design). Wouldn't it be better to pull down CO2 instead. I considered a feed from the CO2 cylinder but then remembered there's CO2 in the sump return chamber.
I routed a 3/4" pipe from a bulkhead fitting in the return chamber into the top of the standpipe in place of the vent so creating a sealed loop. At last, CO2 came up rapidly. I had to go to work in the afternoon so I don't know what it peaked at but when I came in this evening CO2 was still right up, 2 hours after it shut off, and I think I may have overdone it

. KH is 7˝ and pH is 6.58 at the moment and my CO2 drop test is the lightest of green, almost yellow. I'll have to back it off a lot.
Thanks for your advice Tom.
The tank has only been running a fortnight. At the moment I'm restricting lighting to 2 hours in the evening and changing water every 2/3 days. It's fairly well planted with fast growers (cabomba, ceratophyllum, three types of hygrophila) but I've still got some more for which I'm awaiting delivery. I've put in half a dozen shrimps and 4 nerite snails last week and two dozen small fish yesterday (blank neons and white cloud mountain minnows)
What do you recommend for increasing the light period, an extra hour every week?
Brian.
515L tank running on a 90L sump, CO2, 3 70w 5200k MHs, Aqua Medic Volcanit substrate, EI ferts
Juwel Trigon 190L corner tank, Dennerle Deponit substrate, 70w 5200k MH, planted, CO2 & EI ferts.
45L & 70L tanks, non- CO2, EI 'light' using Excel